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Cyclic and Cubic Organophosphonates of Gallium and Their Relationship to Structural Motifs in Gallophosphate Molecular Sieves
Author(s) -
Mason Mark R.,
Mashuta Mark S.,
Richardson John F.
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199702391
Subject(s) - molecular sieve , gallium , crystallography , materials science , chemistry , organic chemistry , catalysis , metallurgy
A potential precursor to new gallophosphate materials . The Cubic Ga 4 P 4 O 12 unit common to several gallophosphate molecular sieves has now been prepared in a soluble, molecular form. On the right is shown the Ga 4 P 4 O 12 core of [ t BuGa(μ 3 ‐O 3 PPh)] 4 as confirmed by X‐ray crystallography.