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Phosphinidine‐Bridged Silver Clusters
Author(s) -
Fenske Dieter,
Simon Falk
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199702301
Subject(s) - stoichiometry , cluster (spacecraft) , crystallography , chemistry , silver salts , inorganic chemistry , computer science , programming language
Clusters containing 18, 45, and 50 silver atoms can be synthesized from the reaction of AgCl with PhP(SiMe 3 ) 2 in the presence of P n Pr 3 . The structures of the phosphinidine‐bridged silver clusters formed depends upon the temperature and the stoichiometric ratio of the reactants. [ Ag 50 (PPh) 20 Cl 7 P(P n Pr 3 ) 13 ] is the biggest known silver cluster and one of the largest structurally characterized cluster complexes to date.