Aggregation and Redox‐Disproportionation in Tripodal Indium and Thallium Amides: First Characterization of Mixed‐Valent M I /M II  Compounds (M = In, Tl) | Zendy

Hellmann Konrad W. | Zendy; Gade Lutz H. | Zendy; Steiner Alexander | Zendy; Stalke Dietmar | Zendy; Möller Frank | Zendy

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Aggregation and Redox‐Disproportionation in Tripodal Indium and Thallium Amides: First Characterization of Mixed‐Valent M I /M II Compounds (M = In, Tl)

Author(s) -

Hellmann Konrad W.,

Gade Lutz H.,

Steiner Alexander,

Stalke Dietmar,

Möller Frank

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199701601

Subject(s) - disproportionation , chemistry , redox , metal , amide , thallium , yield (engineering) , indium , inorganic chemistry , tris , lithium (medication) , lithium amide , crystallography , medicinal chemistry , materials science , organic chemistry , catalysis , medicine , biochemistry , enantioselective synthesis , metallurgy , endocrinology

Aggregation through weak metal–metal contacts as well as redox disproportionations are the chemical characteristics of the metal exchange products of the tripodal tris(lithium amide)s [H 3 CC{CH 2 N(Li)SiMe 3 } 3 (L) 3 ] (L=dioxane, THF) with MCl (M = In, Tl). These reactions yield the first examples of mixed‐valent M I /M II compounds like [H 3 CC(CH 2 NSiMe 3 ) 3 Tl 2 ] 2 (see structure on the right).

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