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Synthesis and Coordination Chemistry of Fluorine‐Containing Cages
Author(s) -
Plenio Herbert,
Diodone Ralph,
Badura Dirk
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199701561
Subject(s) - fluorine , covalent bond , chemistry , ligand (biochemistry) , coordination complex , ion , coordination number , metal , crystallography , inorganic chemistry , organic chemistry , biochemistry , receptor
Covalently bound fluorine atoms are effective donors! This is demonstrated by the F 4 O 3 N 1 coordination of the Cs + ion in the complex with the macropolycyclic ligand 1 . Three of the four shortest bonds to the metal ion are Cs + F bonds, and one of these is extremely short (284.2(3)pm).