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Ene Reactions of Alkynes for the Stereoselective Synthesis of Allylamines
Author(s) -
Ofial Armin R.,
Mayr Herbert
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199701431
Subject(s) - stereoselectivity , ene reaction , chemistry , stereochemistry , organic chemistry , catalysis
Counterion in control! When complex anions with low nucleophilicity are used, a previously unkown ene reaction of iminium ions and alkynes occurs [Eq. (a)], which provides straightforward stereo‐ and regioselective access to substituted allylamines.