Unconventional Amphiphilic Polymers Based on Chiral Polyethylene Oxides | Zendy

Janssen Henk M. | Zendy; Peeters Emiel | Zendy; van Zundert Marga F. | Zendy; van Genderen Marcel H. P. | Zendy; Meijer E. W. | Zendy

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Unconventional Amphiphilic Polymers Based on Chiral Polyethylene Oxides

Author(s) -

Janssen Henk M.,

Peeters Emiel,

van Zundert Marga F.,

van Genderen Marcel H. P.,

Meijer E. W.

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199701221

Subject(s) - amphiphile , polymer , macromolecule , random coil , polar , polyethylene , aqueous solution , polymer chemistry , materials science , polymer science , chain (unit) , chemistry , chemical engineering , organic chemistry , chemical physics , copolymer , stereochemistry , circular dichroism , physics , biochemistry , astronomy , engineering

Regular repeats of polar (P) and apolar units (A) in the main chain of polyethylene oxides earmark a new class of amphiphilic polymers. This primary structure was designed in analogy to peptides that form coiled‐coil structures. In aqueous solution these macromolecules undergo a transition from random coil to helical conformations prior to phase separation.

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