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The First Large‐Pore Vanadosilicate Framework Containing Hexacoordinated Vanadium
Author(s) -
Rocha João,
Brandão Paula,
Lin Zhi,
Anderson Michael W.,
Alfredsson Viveka,
Terasaki Osamu
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199701001
Subject(s) - vanadium , microporous material , materials science , crystallography , electron micrographs , stoichiometry , chemical engineering , mineralogy , chemistry , electron microscope , metallurgy , composite material , optics , physics , engineering
A structure similar to that of microporous titanosilicate ETS‐10 is reported for the first large‐pore vanadosilicate framework containing stoichiometric amounts of hexacoordinated vanadium. A section of the high‐resolution electron micrograph of the vanadosilicate is shown on the right.