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The First 2‐Carba‐ nido ‐pentaborane(8) Derivative; Structure of Sodium Hexaethyl‐2, 4‐Dicarba‐ nido ‐hexaborate(1 −)
Author(s) -
Wrackmeyer Bernd,
Schanz HansJörg,
Milius Wolfgang
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199700751
Subject(s) - deprotonation , chemistry , carborane , derivative (finance) , sodium , carbon atom , methanol , carbon fibers , salt (chemistry) , sodium salt , medicinal chemistry , stereochemistry , crystallography , inorganic chemistry , organic chemistry , ring (chemistry) , materials science , ion , composite number , financial economics , economics , composite material
Integration of a carbon atom in the carborane cage is the key feature of the deprotonation of 1 with Na[Et 3 BH] to give the sodium salt 2 . The process is reversible: treatment of 2 with methanol leads to the reformation of 1 .