The First 2‐Carba‐ nido ‐pentaborane(8) Derivative; Structure of Sodium Hexaethyl‐2, 4‐Dicarba‐ nido ‐hexaborate(1 −) | Zendy

Wrackmeyer Bernd | Zendy; Schanz HansJörg | Zendy; Milius Wolfgang | Zendy

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The First 2‐Carba‐ nido ‐pentaborane(8) Derivative; Structure of Sodium Hexaethyl‐2, 4‐Dicarba‐ nido ‐hexaborate(1 −)

Author(s) -

Wrackmeyer Bernd,

Schanz HansJörg,

Milius Wolfgang

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199700751

Subject(s) - deprotonation , chemistry , carborane , derivative (finance) , sodium , carbon atom , methanol , carbon fibers , salt (chemistry) , sodium salt , medicinal chemistry , stereochemistry , crystallography , inorganic chemistry , organic chemistry , ring (chemistry) , materials science , ion , composite number , financial economics , economics , composite material

Integration of a carbon atom in the carborane cage is the key feature of the deprotonation of 1 with Na[Et 3 BH] to give the sodium salt 2 . The process is reversible: treatment of 2 with methanol leads to the reformation of 1 .

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