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[(η 5 ‐C 5 Me 5 )AlFe(CO) 4 ]—Synthesis, Structure, and Bonding
Author(s) -
Weiss Jurij,
Stetzkamp Dana,
Nuber Bernhard,
Fischer Roland A.,
Boehme Christian,
Frenking Gernot
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199700701
Subject(s) - chemistry , crystallography , acceptor , x ray crystallography , materials science , diffraction , physics , optics , condensed matter physics
The bonding in the unprecedented complex [Cp * AlFe(CO) 4 ] (depicted on the right) was investigated by quantum theoretical methods by using the model compound [CpAlFe(CO) 4 ]. The strength of Al → Fe donor – acceptor bond, which is characteristic for this complex, is estimated to be about 50 kcal mol −1 .
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