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Tl I [C(SiMe 3 ) 3 ]—An Alkylthallium( I ) Compound with a Distorted Tetrahedron of Tl Atoms in the Solid State
Author(s) -
Uhl Werner,
Keimling Sven Uwe,
Klinkhammer Karl Wilhelm,
Schwarz Wolfgang
Publication year - 1997
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199700641
Subject(s) - thallium , methyllithium , tetrahedron , chemistry , crystallography , trimethylsilyl , solid state , monomer , inorganic chemistry , stereochemistry , medicinal chemistry , organic chemistry , polymer
Weak thallium–thallium interactions are present in the thallium tetrahedron of the crystalline alkylthallium( I ) compound Tl[C(SiMe 3 ) 3 ], which is easily accessible from cyclopentadienylthallium( I ) and tris(trimethylsilyl)methyllithium. In solution, however, only the monomer of the extremely thermally sensitive compound can be detected.