Tl I [C(SiMe 3 ) 3 ]—An Alkylthallium( I ) Compound with a Distorted Tetrahedron of Tl Atoms in the Solid State | Zendy

Uhl Werner | Zendy; Keimling Sven Uwe | Zendy; Klinkhammer Karl Wilhelm | Zendy; Schwarz Wolfgang | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Tl I [C(SiMe 3 ) 3 ]—An Alkylthallium( I ) Compound with a Distorted Tetrahedron of Tl Atoms in the Solid State

Author(s) -

Uhl Werner,

Keimling Sven Uwe,

Klinkhammer Karl Wilhelm,

Schwarz Wolfgang

Publication year - 1997

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199700641

Subject(s) - thallium , methyllithium , tetrahedron , chemistry , crystallography , trimethylsilyl , solid state , monomer , inorganic chemistry , stereochemistry , medicinal chemistry , organic chemistry , polymer

Weak thallium–thallium interactions are present in the thallium tetrahedron of the crystalline alkylthallium( I ) compound Tl[C(SiMe 3 ) 3 ], which is easily accessible from cyclopentadienylthallium( I ) and tris(trimethylsilyl)methyllithium. In solution, however, only the monomer of the extremely thermally sensitive compound can be detected.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research