[As 2 (AlCp * ) 3 ]—A Compound with a Polyhedral As 2 Al 3  Framework | Zendy

von Hänisch Carsten K. F. | Zendy; Üffing Christoph | Zendy; Junker Markus A. | Zendy; Ecker Achim | Zendy; Kneisel Boris O. | Zendy; Schnöckel Hansgeorg | Zendy

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[As 2 (AlCp * ) 3 ]—A Compound with a Polyhedral As 2 Al 3 Framework

Author(s) -

von Hänisch Carsten K. F.,

Üffing Christoph,

Junker Markus A.,

Ecker Achim,

Kneisel Boris O.,

Schnöckel Hansgeorg

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199628751

Subject(s) - borane , crystallography , group (periodic table) , pentagonal bipyramidal molecular geometry , main group element , trigonal bipyramidal molecular geometry , chemistry , quantum chemical , bipyramid , molecule , crystal structure , materials science , transition metal , biochemistry , organic chemistry , catalysis

The bonding in heteropolyhedral compounds of the closo ‐borane type is discussed for “As 2 (AlCp * ) 3 ” clusters, whose molecular structure has been characterized by X‐ray crystallography (framework shown on the right). Quantum chemical calculations on several trigonal‐bipyramidal E 2 V E 3 IIIstructures revealed the mode of bonding for a variety of ligands (Cp * = C 5 Me 5 ; E III : Group 13 element, E V : Group 15 element).

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