Synthesis and Characterization of the Stable Dicarbonyl(cyclopentadienyl)iron Radical [(C 5 R 5 )Fe(CO) 2 ] (R  CHMe 2 ) | Zendy

Sitzmann Helmut | Zendy; Dezember Thomas | Zendy; Kaim Wolfgang | Zendy; Baumann Frank | Zendy; Stalke Dietmar | Zendy; Kärcher Joerg | Zendy; Dormann Elmar | Zendy; Winter Hubert | Zendy; Wachter Christoph | Zendy; Kelemen Marc | Zendy

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Synthesis and Characterization of the Stable Dicarbonyl(cyclopentadienyl)iron Radical [(C 5 R 5 )Fe(CO) 2 ] (R  CHMe 2 )

Author(s) -

Sitzmann Helmut,

Dezember Thomas,

Kaim Wolfgang,

Baumann Frank,

Stalke Dietmar,

Kärcher Joerg,

Dormann Elmar,

Winter Hubert,

Wachter Christoph,

Kelemen Marc

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199628721

Subject(s) - cyclopentadienyl complex , monomer , carbonylation , chemistry , crystal structure , characterization (materials science) , medicinal chemistry , crystallography , materials science , catalysis , carbon monoxide , organic chemistry , polymer , nanotechnology

Monomeric in solution, dimeric in the crystal is the dicarbonyl(pentaisopropyl‐cyclopentadienyl)iron( I ) radical 2 , which is formed from the high‐spin iron( II ) complex 1 by carbonylation and reduction.

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