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Synthesis and Characterization of the Stable Dicarbonyl(cyclopentadienyl)iron Radical [(C 5 R 5 )Fe(CO) 2 ] (R CHMe 2 )
Author(s) -
Sitzmann Helmut,
Dezember Thomas,
Kaim Wolfgang,
Baumann Frank,
Stalke Dietmar,
Kärcher Joerg,
Dormann Elmar,
Winter Hubert,
Wachter Christoph,
Kelemen Marc
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199628721
Subject(s) - cyclopentadienyl complex , monomer , carbonylation , chemistry , crystal structure , characterization (materials science) , medicinal chemistry , crystallography , materials science , catalysis , carbon monoxide , organic chemistry , polymer , nanotechnology
Monomeric in solution, dimeric in the crystal is the dicarbonyl(pentaisopropyl‐cyclopentadienyl)iron( I ) radical 2 , which is formed from the high‐spin iron( II ) complex 1 by carbonylation and reduction.