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New Imido‐Bridged Transition Metal Clusters: [(C 5 H 5 ) 4 Ti 4 (NSnMe 3 ) 4 ], [Co 11 (PPh 3 ) 3 (NPh) 12 ], [Ni 11 Br 6 (N t Bu) 8 ], and [Li(thf) 4 ] 4 [Cu 24 (NPh) 14 ]
Author(s) -
Decker Andrea,
Fenske Dieter,
Maczek Klaus
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199628631
Subject(s) - transition metal , halide , crystallography , metal , chemistry , ion , cluster (spacecraft) , inorganic chemistry , materials science , catalysis , organic chemistry , computer science , programming language
Metal halide complexes and functionalized amines react to form imidobridged transition metal clusters. This method can be used to synthesize imido clusters of electron‐rich transition metals such as [Li(thf) 4 ] 4 ‐“Cu 24 (μ 3 ‐NPh) 8 μ 4 ‐NPh) 6 ” 1 (the structure of the anion of 1 is depicted on the right).