New Imido‐Bridged Transition Metal Clusters: [(C 5 H 5 ) 4 Ti 4 (NSnMe 3 ) 4 ], [Co 11 (PPh 3 ) 3 (NPh) 12 ], [Ni 11 Br 6 (N t Bu) 8 ], and [Li(thf) 4 ] 4 [Cu 24 (NPh) 14 ] | Zendy

Decker Andrea | Zendy; Fenske Dieter | Zendy; Maczek Klaus | Zendy

Premium

New Imido‐Bridged Transition Metal Clusters: [(C 5 H 5 ) 4 Ti 4 (NSnMe 3 ) 4 ], [Co 11 (PPh 3 ) 3 (NPh) 12 ], [Ni 11 Br 6 (N t Bu) 8 ], and [Li(thf) 4 ] 4 [Cu 24 (NPh) 14 ]

Author(s) -

Decker Andrea,

Fenske Dieter,

Maczek Klaus

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199628631

Subject(s) - transition metal , halide , crystallography , metal , chemistry , ion , cluster (spacecraft) , inorganic chemistry , materials science , catalysis , organic chemistry , computer science , programming language

Metal halide complexes and functionalized amines react to form imidobridged transition metal clusters. This method can be used to synthesize imido clusters of electron‐rich transition metals such as [Li(thf) 4 ] 4 ‐“Cu 24 (μ 3 ‐NPh) 8 μ 4 ‐NPh) 6 ” 1 (the structure of the anion of 1 is depicted on the right).

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research