Premium
From Pagodanes to Nonpentagonal (Homo)Dodecahedranes—The Undecacyclo‐[10.10.0.0 2,20 .0 3,10 .0 4,19 .0 5,9 .0 6,18 .0 7,15 .0 8,13 .0 19,22 .0 16,21 ]docosane Cage
Author(s) -
Sharma Veeraraghava,
Keller Manfred,
Weiler Andreas,
Hunkler Dieter,
Prinzbach Horst
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199628581
Subject(s) - chemistry , methylene , stereochemistry , medicinal chemistry
Twofold, transannular cyclization of the bis(methylene)bisseco intermediates B , obtained from the pagodane diester A , provides access to the parent nonpentagonal bis(homo)dodecahedrane C and pairwise symmetrically functionalized derivatives. Some of these products are important model compounds for quantifying the factors that determine the transannular electronic interactions in cage compounds of this type.