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Te 6 , [Te 8 Cl 18 ] 2− , and [TeCl 3 ] − : New Tellurium and Chlorotellurato Ligands in the Re 6 Solid‐State Cluster Compounds Re 6 Te 16 Cl 18 and Re 6 Te 16 Cl 6
Author(s) -
Mironov Yuri V.,
Pell Michael A.,
Ibers James A.
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199628541
Subject(s) - octahedron , crystallography , tellurium , cluster (spacecraft) , chemistry , ligand (biochemistry) , crystal structure , inorganic chemistry , biochemistry , receptor , computer science , programming language
Re 6 octahedra inside Te 8 cubes is a common feature of both title compounds. The picture on the right shows a section of the structure of Re 6 Te 16 Cl 18 , in which the Re 6 octahedron and the binding of the cluster to the [Te 8 Cl 18 ] 2− ligand are apparent. Different binding to ligands results in a three‐dimensional structure for Re 6 Te 16 Cl 18 , and a two‐dimensional structure for Re 6 Te 16 Cl 6 .