Te 6 , [Te 8 Cl 18 ] 2− , and [TeCl 3 ] − : New Tellurium and Chlorotellurato Ligands in the Re 6  Solid‐State Cluster Compounds Re 6 Te 16 Cl 18  and Re 6 Te 16 Cl 6 | Zendy

Mironov Yuri V. | Zendy; Pell Michael A. | Zendy; Ibers James A. | Zendy

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Te 6 , [Te 8 Cl 18 ] 2− , and [TeCl 3 ] − : New Tellurium and Chlorotellurato Ligands in the Re 6 Solid‐State Cluster Compounds Re 6 Te 16 Cl 18 and Re 6 Te 16 Cl 6

Author(s) -

Mironov Yuri V.,

Pell Michael A.,

Ibers James A.

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199628541

Subject(s) - octahedron , crystallography , tellurium , cluster (spacecraft) , chemistry , ligand (biochemistry) , crystal structure , inorganic chemistry , biochemistry , receptor , computer science , programming language

Re 6 octahedra inside Te 8 cubes is a common feature of both title compounds. The picture on the right shows a section of the structure of Re 6 Te 16 Cl 18 , in which the Re 6 octahedron and the binding of the cluster to the [Te 8 Cl 18 ] 2− ligand are apparent. Different binding to ligands results in a three‐dimensional structure for Re 6 Te 16 Cl 18 , and a two‐dimensional structure for Re 6 Te 16 Cl 6 .

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