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First Phenylene Polymers Linked by Sulfonium Groups
Author(s) -
Tsuchida Eishun,
Yamamoto Kimihisa,
Miyatake Kenji,
Nishimura Yukio
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199628431
Subject(s) - sulfonium , monomer , phenylene , sulfonate , polymer chemistry , ether , benzene , polymer , p xylene , chemistry , poly(p phenylene) , sodium , xylene , polymerization , organic chemistry , toluene , salt (chemistry)
Alternating phenylene units and methylsulfonium groups make up polymer 1 , which is formed by polymerizing benzene with sodium methanesulfinate. This reaction is conducted in trifluoromethane‐sulfonate, and xylene and diphenyl ether are also suitable monomers.