Supramolecular Host–Guest Compounds with Tripod–Metal Templates as Building Blocks at the Corners | Zendy

Mann Susanne | Zendy; Huttner Gottfried | Zendy; Zsolnai Laszlo | Zendy; Heinze Katja | Zendy

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Supramolecular Host–Guest Compounds with Tripod–Metal Templates as Building Blocks at the Corners

Author(s) -

Mann Susanne,

Huttner Gottfried,

Zsolnai Laszlo,

Heinze Katja

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199628081

Subject(s) - tripod (photography) , tetrahedron , supramolecular chemistry , template , chemistry , crystallography , host–guest chemistry , metal , nanotechnology , stereochemistry , materials science , crystal structure , organic chemistry , physics , optics

In a one‐pot reaction from 15 components , a tetra‐hedral host‐guest compound forms by self‐assembly. Its tripod–iron( II ) groups are the corners of a tetrahedron (depicted on the right). The edges of the tetrahedron are bridged by 1,2‐dinitrile ligands, and a BF 4 −ion is encapsulated in the tetrahedral cavity.

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