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[(enH 2 ) 0.5 ][Zr 2 (PO 4 ) 2 (HPO 4 )F]·H 2 O: A Unique Zirconium Fluoride Phosphate with a Cavity Structure
Author(s) -
Kemnitz Erhard,
Wloka Martin,
Trojanov Sergej,
Stiewe Anja
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199626771
Subject(s) - octahedron , zirconium , tetrahedron , crystallography , fluoride , zinc phosphate , zinc , materials science , crystal structure , structure type , inorganic chemistry , mineralogy , chemistry , metallurgy
Medium‐sized channels pass through the structure of the first zinc fluoride phosphate (section of the structure is shown on the right). The framework is constructed from ZrO 6 and ZrO 5 F octahedra and PO 4 and PO 3 (OH) tetrahedra. Further cavity‐containing compounds of this type should be accessible by variation of the amine used as a template.
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