Hexaaryltellurium, the First Neutral Compounds Comprising Hexaarylated Elements | Zendy

Minoura Mao | Zendy; Sagami Takao | Zendy; Akiba Kinya | Zendy; Modrakowski Claudia | Zendy; Sudau Allexander | Zendy; Seppelt Konrad | Zendy; Wallenhauer Stephan | Zendy

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Hexaaryltellurium, the First Neutral Compounds Comprising Hexaarylated Elements

Author(s) -

Minoura Mao,

Sagami Takao,

Akiba Kinya,

Modrakowski Claudia,

Sudau Allexander,

Seppelt Konrad,

Wallenhauer Stephan

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199626601

Subject(s) - tellurium , crystallography , oxidation state , symmetry (geometry) , chemistry , center (category theory) , materials science , stereochemistry , inorganic chemistry , mathematics , geometry , organic chemistry , catalysis

The highest possible oxidation state of +6 is displayed by the tellurium center in the hexaaryltellurium compounds 1 a and 1 b . Both are extremely thermally stable and, unlike other organotellurium compounds, not light‐sensitive. X‐ray crystallographic analyses of 1 revealed rare examples of approximate T h molecular symmetry.

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