Synthesis and Structure of CoB 2 P 3 O 12 (OH)·C 2 H 10 N 2 : The First Metal Borophosphate with an Open Framework Structure | Zendy

Sevov Slavi C. | Zendy

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Synthesis and Structure of CoB 2 P 3 O 12 (OH)·C 2 H 10 N 2 : The First Metal Borophosphate with an Open Framework Structure

Author(s) -

Sevov Slavi C.

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199626301

Subject(s) - octahedron , ethylenediamine , crystallography , hydrothermal synthesis , tetrahedron , microporous material , hydrothermal circulation , metal , materials science , chemistry , crystal structure , inorganic chemistry , geology , seismology , metallurgy , composite material

Channels measuring roughly 5.2 × 7.6 Å (OO distances) are found in the first microporous borophosphate (a section of the structure is shown on the right). Ethylenediamine serves as a template in the hydrothermal synthesis. The framework is constructed from BO 4 and PO 4 tetrahedra and CoO 6 octahedra, and organic dications occupy the channels.

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