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Synthesis and Structure of CoB 2 P 3 O 12 (OH)·C 2 H 10 N 2 : The First Metal Borophosphate with an Open Framework Structure
Author(s) -
Sevov Slavi C.
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199626301
Subject(s) - octahedron , ethylenediamine , crystallography , hydrothermal synthesis , tetrahedron , microporous material , hydrothermal circulation , metal , materials science , chemistry , crystal structure , inorganic chemistry , geology , seismology , metallurgy , composite material
Channels measuring roughly 5.2 × 7.6 Å (OO distances) are found in the first microporous borophosphate (a section of the structure is shown on the right). Ethylenediamine serves as a template in the hydrothermal synthesis. The framework is constructed from BO 4 and PO 4 tetrahedra and CoO 6 octahedra, and organic dications occupy the channels.