Large Sulfur–Nitrogen Heterocycles: Preparation of the Sulfur Imides S  n  NH ( n  = 8, 9, 11) and Structures of S 8 NH and S 9 NH | Zendy

Steudel Ralf | Zendy; Bergemann Klaus | Zendy; Buschmann Jürgen | Zendy; Luger Peter | Zendy

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Large Sulfur–Nitrogen Heterocycles: Preparation of the Sulfur Imides S n NH ( n = 8, 9, 11) and Structures of S 8 NH and S 9 NH

Author(s) -

Steudel Ralf,

Bergemann Klaus,

Buschmann Jürgen,

Luger Peter

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199625371

Subject(s) - sulfur , nitrogen , chemistry , ligand (biochemistry) , inorganic chemistry , crystallography , organic chemistry , biochemistry , receptor

A surprisingly simple, systematic route to the title compounds is achieved by ligand transfer from [Cp 2 TiS 7 NH] to the difunctional sulfanes Sn n Cl 2 ( n = 1, 2). This should provide new impetus to sulfur–nitrogen chemistry. Whereas the structure of S 9 NH (shown on the right) is significantly different from that of S 10 , the structure of S 8 NH resembles that of S 9 .

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