Premium
Large Sulfur–Nitrogen Heterocycles: Preparation of the Sulfur Imides S n NH ( n = 8, 9, 11) and Structures of S 8 NH and S 9 NH
Author(s) -
Steudel Ralf,
Bergemann Klaus,
Buschmann Jürgen,
Luger Peter
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199625371
Subject(s) - sulfur , nitrogen , chemistry , ligand (biochemistry) , inorganic chemistry , crystallography , organic chemistry , biochemistry , receptor
A surprisingly simple, systematic route to the title compounds is achieved by ligand transfer from [Cp 2 TiS 7 NH] to the difunctional sulfanes Sn n Cl 2 ( n = 1, 2). This should provide new impetus to sulfur–nitrogen chemistry. Whereas the structure of S 9 NH (shown on the right) is significantly different from that of S 10 , the structure of S 8 NH resembles that of S 9 .