Premium
Spontaneous Magnetization in a Sulfur–Nitrogen Radical at 36 K
Author(s) -
Banister Arthur J.,
Bricklebank Neil,
Lavender Ian,
Rawson Jeremy M.,
Gregory Christopher I.,
Tanner Brian K.,
Clegg William,
Elsegood Mark R. J.,
Palacio Fernando
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199625331
Subject(s) - orthorhombic crystal system , spontaneous magnetization , magnetization , sublimation (psychology) , antiferromagnetism , sulfur , nitrogen , materials science , crystallography , chemistry , condensed matter physics , nuclear magnetic resonance , crystal structure , physics , organic chemistry , magnetic field , psychology , quantum mechanics , psychotherapist
Slow sublimation of the dithiadiazolyl radical 1 yields crystals of a new polymorph 1β (orthorhombic, space group Fdd2 ). Below 36 K this new phase exhibits a spontaneous magnetic moment, which is described in terms of canted antiferromagnetism.