Spontaneous Magnetization in a Sulfur–Nitrogen Radical at 36 K | Zendy

Banister Arthur J. | Zendy; Bricklebank Neil | Zendy; Lavender Ian | Zendy; Rawson Jeremy M. | Zendy; Gregory Christopher I. | Zendy; Tanner Brian K. | Zendy; Clegg William | Zendy; Elsegood Mark R. J. | Zendy; Palacio Fernando | Zendy

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Spontaneous Magnetization in a Sulfur–Nitrogen Radical at 36 K

Author(s) -

Banister Arthur J.,

Bricklebank Neil,

Lavender Ian,

Rawson Jeremy M.,

Gregory Christopher I.,

Tanner Brian K.,

Clegg William,

Elsegood Mark R. J.,

Palacio Fernando

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199625331

Subject(s) - orthorhombic crystal system , spontaneous magnetization , magnetization , sublimation (psychology) , antiferromagnetism , sulfur , nitrogen , materials science , crystallography , chemistry , condensed matter physics , nuclear magnetic resonance , crystal structure , physics , organic chemistry , magnetic field , psychology , quantum mechanics , psychotherapist

Slow sublimation of the dithiadiazolyl radical 1 yields crystals of a new polymorph 1β (orthorhombic, space group Fdd2 ). Below 36 K this new phase exhibits a spontaneous magnetic moment, which is described in terms of canted antiferromagnetism.

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