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Selective Photocyclization of Glycine in Dipeptides
Author(s) -
Wyss Caroline,
Batra Rohit,
Lehmann Christian,
Sauer Stefan,
Giese Bernd
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199625291
Subject(s) - peptidomimetic , surprise , glycine , selectivity , chemistry , dipeptide , stereochemistry , combinatorial chemistry , peptide , organic chemistry , amino acid , catalysis , psychology , communication , biochemistry
Never failing to surprise —radical reactions with amazing selectivity. Photocyclization of the modified dipeptides 1 proceeds via biradicals that cyclize to give the peptidomimetics 2 . Z benzyloxycarbonyl.