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Fast Atom Bombardment Mass Spectrometry for Characterizing Cationic Chelated Species
Author(s) -
Whiteford Jeffery A.,
Rachlin Elliot M.,
Stang Peter J.
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199625241
Subject(s) - fast atom bombardment , cationic polymerization , mass spectrometry , atom (system on chip) , chemistry , isotope , ligand (biochemistry) , chelation , metal , atomic mass , analytical chemistry (journal) , atomic physics , inorganic chemistry , nuclear physics , physics , chromatography , organic chemistry , biochemistry , receptor , computer science , embedded system
Even the metal–ligand coordination in the molecular square 1 is retained in the fragments generated by fast atom bombardment in the mass spectroscopic method described. In this example the M –2OTf peak can be identified unequivocally owing to the peak separation of 0.5 m/z units in the isotopic distribution pattern.