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A Unique Ni II Complex with Three Different Azido Bridges: Magneto‐Structural Correlations in the First Triply Alternating S = 1 Chain
Author(s) -
Ribas Joan,
Monfort Montserrat,
Resino Immaculada,
Solans Xavier,
Rabu Pierre,
Maingot Fabrice,
Drillon Marc
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199625201
Subject(s) - antiferromagnetism , chain (unit) , magneto , crystallography , physics , sequence (biology) , amine gas treating , state (computer science) , solid state , chemistry , materials science , condensed matter physics , stereochemistry , mathematics , magnet , quantum mechanics , engineering physics , biochemistry , organic chemistry , algorithm
A complex sequence of ferro‐ and antiferromagnetic interactions occurs in the compound [Ni( N,N ′‐dmen)(μ‐N 3 ) 2 ] ( N,N ′‐dmen N,N ′‐dimethylethylenediamine), which exists as a one‐dimensional chain in the solid state (shown below; C atoms of the amine ligands are omitted). The magnetic behavior of this unusual spin system has been analyzed in detail.