Solution and Solid‐State Structure of a Lithiated Phosphane Oxide | Zendy

Denmark Scott E. | Zendy; Swiss Kevin A. | Zendy; Wilson Scott R. | Zendy

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Solution and Solid‐State Structure of a Lithiated Phosphane Oxide

Author(s) -

Denmark Scott E.,

Swiss Kevin A.,

Wilson Scott R.

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199625151

Subject(s) - solid state , oxide , carbon atom , crystallography , dimer , chemistry , atom (system on chip) , carbon fibers , group (periodic table) , solid solution , materials science , ring (chemistry) , organic chemistry , composite number , computer science , composite material , embedded system

The anionic benzyl carbon atom is sp 2 hybridized in 1 , the first lithiated phosphane oxide that has been characterized by X‐ray crystallography. In the solid state as well as in THF solution, 1 is shown to exist as a dimer with no LiC contacts. Unlike related phosphonamides, 1 prefers an orthogonal conformation of the benzylic group in the solid state.

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