Self‐Assembling Covalently Linked Supramolecular Arrays of Defined Structure: The Remarkable Redox Reactivity of 15‐ meso ‐Substituted 5‐Oxyporphyrins | Zendy

Khoury Richard G. | Zendy; Jaquinod Laurent | Zendy; Nurco Daniel J. | Zendy; Pandey Ravindra K. | Zendy; Senge Mathias O. | Zendy; Smith Kevin M. | Zendy

Premium

Self‐Assembling Covalently Linked Supramolecular Arrays of Defined Structure: The Remarkable Redox Reactivity of 15‐ meso ‐Substituted 5‐Oxyporphyrins

Author(s) -

Khoury Richard G.,

Jaquinod Laurent,

Nurco Daniel J.,

Pandey Ravindra K.,

Senge Mathias O.,

Smith Kevin M.

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199624961

Subject(s) - supramolecular chemistry , redox , covalent bond , chemistry , reactivity (psychology) , molecule , hexane , self assembly , crystallography , crystal structure , polymer chemistry , stereochemistry , photochemistry , organic chemistry , medicine , pathology , alternative medicine

Oxidation at position 10 converts the title compounds into dimers. In an extension of this reaction a 15,15′‐ p ‐phenylene‐linked bis(oxophlorin) produces the robust supramolecular array tetrakis(isooxophlorin) 1 . In the crystal 1 has an overall helical structure in which the groove is filled by molecules of n ‐hexane.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research