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Complexes Containing Phosphorus and Arsenic as Terminal Ligands
Author(s) -
Scheer Manfred,
Müller Jan,
Häser Marco
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199624921
Subject(s) - arsenic , chemistry , pnictogen , phosphorus , terminal (telecommunication) , lewis acids and bases , chemical stability , stereochemistry , inorganic chemistry , organic chemistry , catalysis , superconductivity , physics , computer science , telecommunications , quantum mechanics
Complexes with terminal pnictide ligands are interesting in themselves and as ligands for the complexation of Lewis acids. Herein the syntheses of complexes such as 1 (E P, As) and 2 (M Cr, W) are described, and detailed theoretical studies on the relative thermodynamic stability of these and analogously constructed complexes are presented.