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Late Transition Metal Complexes: Catalysts for a New Generation of Organic Polymers
Author(s) -
AbuSurrah Adnan S.,
Rieger Bernhard
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199624751
Subject(s) - carbon monoxide , copolymer , catalysis , transition metal , propene , polymer chemistry , polymer , palladium , metal , chemistry , materials science , organic chemistry
Long‐chain‐branched copolymers 2 can be prepared from ethene and acrylates (R′ Me, t Bu, CH 2 (CF 2 ) 6 CF 3 ) with the Pd II catalysts 1 . Copolymers of this type were previously produced exclusively by radical routes in high‐pressure processes. Propene/carbon monoxide copolymers (polyketones) have been obtained with other Pd II complexes.