The Existence of Stable Tm@C 82  Isomers | Zendy

Kirbach Uwe | Zendy; Dunsch Lothar | Zendy

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The Existence of Stable Tm@C 82 Isomers

Author(s) -

Kirbach Uwe,

Dunsch Lothar

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199623801

Subject(s) - cyclic voltammetry , fullerene , chemistry , carbon fibers , spectroscopy , symmetry (geometry) , endohedral fullerene , high performance liquid chromatography , analytical chemistry (journal) , computational chemistry , crystallography , materials science , chromatography , organic chemistry , electrochemistry , electrode , physics , mathematics , composite material , quantum mechanics , composite number , geometry

Endohedral fullerene compounds with isomeric carbon frameworks have been identified for the first time. The three stable isomers of Tm 2+ @C 82 2−were separated by HPLC, and characterized by cyclic voltammetry and by UV/Vis/NIR and 13 C NMR spectroscopy as probably having C 2 , C s , and C 3v symmetry (see picture).

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