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Crystal Structures and Properties of Cyclic Polyenes Possessing Disulfide Units
Author(s) -
Shimizu Toshio,
Iwata Kazuko,
Kamigata Nobumasa
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199623571
Subject(s) - tetramer , disulfide bond , acetonitrile , crystal structure , chloroform , molecule , chemistry , crystallography , stereochemistry , organic chemistry , biochemistry , enzyme
Tetrathiocin 1 and the tetramer 2 could be synthesized oxidatively from ethenedithiolate and were successfully characterized. Compound 2 with its cage structure can be considered as a new type of host molecule. It also forms from 1 , which has a twisted structure, in acetonitrile/chloroform.
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