A New In 4  Cluster with Short InIn Bonds in Trigonal‐Planar In(InTrip 2 ) 3 | Zendy

Brothers Penelope J. | Zendy; Hübler Klaus | Zendy; Hübler Ute | Zendy; Noll Bruce C. | Zendy; Olmstead Marilyn M. | Zendy; Power Philip P. | Zendy

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A New In 4 Cluster with Short InIn Bonds in Trigonal‐Planar In(InTrip 2 ) 3

Author(s) -

Brothers Penelope J.,

Hübler Klaus,

Hübler Ute,

Noll Bruce C.,

Olmstead Marilyn M.,

Power Philip P.

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199623551

Subject(s) - indium , crystallography , planar , gallium , cluster (spacecraft) , lithium (medication) , metal , chemistry , indane , trigonal prismatic molecular geometry , materials science , inorganic chemistry , stereochemistry , crystal structure , metallurgy , octahedron , computer graphics (images) , computer science , programming language , endocrinology , medicine

Trigonal‐planar coordination is seen for the indium center in In(InTrip 2 ) 3 ( 1 ) (Trip 2,4,6‐ i Pr 3 C 6 H 2 ), the first indane with three unusually short bonds to indium substituents. The compound is obtained by the reduction of the diindane Trip 2 InInTrip 2 with lithium metal. In contrast, reduction of the aluminum and gallium analogs gives the [Trip 2 MMTrip 2 ] − anions, which have a MM π‐bond order of 0.5.

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