Bimetallic Hydroformylation Catalysis: In Situ Characterization of a Dinuclear Rhodium( II ) Dihydrido Complex with the Largest Rh–HNMR Coupling Constant | Zendy

Matthews Rhonda C. | Zendy; Howell Donna K. | Zendy; Peng WeiJun | Zendy; Train Spencer G. | Zendy; Treleaven W. Dale | Zendy; Stanley George G. | Zendy

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Bimetallic Hydroformylation Catalysis: In Situ Characterization of a Dinuclear Rhodium( II ) Dihydrido Complex with the Largest Rh–HNMR Coupling Constant

Author(s) -

Matthews Rhonda C.,

Howell Donna K.,

Peng WeiJun,

Train Spencer G.,

Treleaven W. Dale,

Stanley George G.

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199622531

Subject(s) - hydroformylation , rhodium , chemistry , bimetallic strip , catalysis , in situ , proton nmr , regioselectivity , polymer chemistry , stereochemistry , organic chemistry

The catalytically active complex in the homogeneously catalyzed, regioselective hydroformylation is possibly the dinuclear complex dication 1 . The 1 J (Rh,H) coupling constant of 164 Hz is the largest such value ever reported and may be a distinctive marker for dinuclear Rh II complexes with terminal hydrido ligands.

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