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From 1σ 4 , 2σ 2 to 1σ 4 , 2σ n ‐Diphosphetes ( n = 3–6): The Surprising Persistence of the PP bond
Author(s) -
Sanchez Muriel,
Réau Régis,
Dahan Françoise,
Regitz Manfred,
Bertrand Guy
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199622281
Subject(s) - physics , ring (chemistry) , chemistry , organic chemistry
Without destruction of the four‐membered ring skeleton , the σ 2 ‐phosphorus atom of a 1 σ 4 ,2σ 2 ‐diphosphete can extend its coordination number up to six (as the series below shows)!
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