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The First Metallacrown Ether Sandwich Complex
Author(s) -
Saalfrank Rolf W.,
Löw Norbert,
Hampel Frank,
Stachel HansDietrich
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199622091
Subject(s) - crown ether , ether , chemistry , crystallography , polymer chemistry , organic chemistry , ion
New blood for crown ether chemistry! Beside the well‐known organocrown ether sandwich complexes 1 there now exist topologically equivalent metallacrown ether complexes 2 . These metallasandwich complexes are generated in a one‐pot reaction by spontanous self‐assembly and in one case have been unambiguously characterized by a crystallographic structure analysis.
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