A Neutral, Triple‐Helical, Trinuclear, Oxo‐Centered Mixed‐Valence Iron Complex | Zendy

Saalfrank Rolf W. | Zendy; Trummer Stefan | Zendy; Krautscheid Harald | Zendy; Schünemann Volker | Zendy; Trautwein Alfred X. | Zendy; Hien Stefan | Zendy; Stadler Christian | Zendy; Daub Jörg | Zendy

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A Neutral, Triple‐Helical, Trinuclear, Oxo‐Centered Mixed‐Valence Iron Complex

Author(s) -

Saalfrank Rolf W.,

Trummer Stefan,

Krautscheid Harald,

Schünemann Volker,

Trautwein Alfred X.,

Hien Stefan,

Stadler Christian,

Daub Jörg

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199622061

Subject(s) - valence (chemistry) , crystallography , ion , chemistry , coordination sphere , ligand (biochemistry) , triple helix , stereochemistry , crystal structure , biochemistry , receptor , organic chemistry

Reminiscent of a windmill , the novel triple‐helicate [(Fe III ) 2 Fe II OL 3 ] 1 , a neutral oxo‐centered mixed‐valence complex, is formed in a one‐pot reaction by self‐assembly. The pentadentate ligand L acts in a tritopic fashion and connects the three iron ions in a triangular plane. At the center of 1 lies μ 3 ‐O 2 ‐ ion. The structural similarity of 1 with trinuclear carboxylatoiron complexes is striking.

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