Programming a Hydrogen‐Bonding Code for the Specific Generation of a Supermacrocycle | Zendy

Mascal Mark | Zendy; Hext Nicholas M. | Zendy; Warmuth Ralf | Zendy; Moore Madeleine H. | Zendy; Turkenburg Johan P. | Zendy

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Programming a Hydrogen‐Bonding Code for the Specific Generation of a Supermacrocycle

Author(s) -

Mascal Mark,

Hext Nicholas M.,

Warmuth Ralf,

Moore Madeleine H.,

Turkenburg Johan P.

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199622041

Subject(s) - nucleobase , guanine , hydrogen bond , cytosine , crystallography , dna , hexagonal crystal system , base pair , solid state , code (set theory) , base (topology) , crystal (programming language) , chemistry , materials science , computer science , stereochemistry , molecule , mathematics , nucleotide , biochemistry , programming language , organic chemistry , mathematical analysis , gene , set (abstract data type)

Infinite channels with a diameter 10.5 Å are formed by the DNA‐base hybrid 1 in the solid state. These channels arise because 1 specifically communicates the hydrogen bonding codes of the nucleobases cytosine and guanine (“C” and “G”) to unambiguously assemble hexagonal, macrocyclic aggregates 1 6 , which overlap in the crystal.

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