Premium
Synthesis and Structure of a Unique Monomeric σ‐Bonded Aryllithium Compound Stabilized by a Weak Li—Benzene π Interaction
Author(s) -
Schiemenz Berthold,
Power Philip P.
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199621501
Subject(s) - monomer , steric effects , benzene , adduct , chemistry , ring (chemistry) , solvation , solid state , stereochemistry , molecule , organic chemistry , polymer
Stabilized only by steric effects and weak solvation by benzene , the aryllithium compound 1 exists as a monomeric benzene adduct. The unique structure of 1 in the solid state is shown on the right; the ortho substituents on the η 1 ‐bound phenyl ring have been omitted for clarity.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom