The Reaction of White Phosphorus with Lithium (Trimethylsilyl)diazomethanide: Direct Access to a New, Aromatic 1,2,3,4‐Diazadiphosphole Ring | Zendy

Charrier Claude | Zendy; Maigrot Nicole | Zendy; Ricard Louis | Zendy; Floch Pascal Le | Zendy; Mathey François | Zendy

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The Reaction of White Phosphorus with Lithium (Trimethylsilyl)diazomethanide: Direct Access to a New, Aromatic 1,2,3,4‐Diazadiphosphole Ring

Author(s) -

Charrier Claude,

Maigrot Nicole,

Ricard Louis,

Floch Pascal Le,

Mathey François

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199621331

Subject(s) - lithium (medication) , trimethylsilyl , ring (chemistry) , white phosphorus , chemistry , cycloaddition , phosphorus , medicinal chemistry , counterion , aromaticity , ion , organic chemistry , catalysis , molecule , psychology , psychiatry

A formal [2 + 3]cycloaddition between [PP] and a diazomethyl anion affords the anionic, aromatic five‐membered ring [RCP 2 N 2 ] − (R = Me 3 Si) [Eq. (a); counterion Li + ]. This reaction is a rare example of the use of P 4 in organic synthesis.

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