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Dibromine Monoxide, Br 2 O, and Bromine Dioxide, OBrO: Spectroscopic Properties, Molecular Structures, and Harmonic Force Fields
Author(s) -
Müller Holger S. P.,
Miller Charles E.,
Cohen Edward A.
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199621291
Subject(s) - bromine , molecule , carbon monoxide , gas phase , chemistry , phase (matter) , inorganic chemistry , organic chemistry , catalysis
Two bromine oxides with more than two atoms have been structurally characterized for the first time in the gas phase (see picture on the right; top: Br 2 O, bottom: OBrO). Both molecules occur over a solid product formed in the reaction of O and Br 2 . Under certain conditions BrO, OBrO, and Br 2 O were obtained simultaneously.
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