First‐Generation Tethered [2.2]Metacyclophanes—Prototypes of Molecular Devices | Zendy

Bodwell Graham J. | Zendy; Houghton Tom J. | Zendy; Kennedy Jason W. J. | Zendy; Mannion Michael R. | Zendy

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First‐Generation Tethered [2.2]Metacyclophanes—Prototypes of Molecular Devices

Author(s) -

Bodwell Graham J.,

Houghton Tom J.,

Kennedy Jason W. J.,

Mannion Michael R.

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199621211

Subject(s) - cyclophane , chemistry , stereochemistry , atom (system on chip) , series (stratigraphy) , crystallography , crystal structure , biology , computer science , paleontology , embedded system

The tether length determines the conformation of [2.2]metacyclophane 1 . The cyclophane with the 13‐atom tether ( n = 11) exists at room temperature as an equilibrium mixture of syn and anti isomers (ca. 5.9:1), whereas the next lower homologue ( n = 10) in this series adopts only the syn conformation and the next higher homologue ( n = 12) solely the anti conformation.

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