Synergy between Magnetic Interaction and Spin Crossover in an Iron( III ) Complex with an Organic Radical as Ligand | Zendy

Sutter JeanPascal | Zendy; Fettouhi Mohammed | Zendy; Li Licun | Zendy; Michaut Cécile | Zendy; Ouahab Lahcéne | Zendy; Kahn Olivier | Zendy

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Synergy between Magnetic Interaction and Spin Crossover in an Iron( III ) Complex with an Organic Radical as Ligand

Author(s) -

Sutter JeanPascal,

Fettouhi Mohammed,

Li Licun,

Michaut Cécile,

Ouahab Lahcéne,

Kahn Olivier

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199621131

Subject(s) - pyridinium , spin crossover , ligand (biochemistry) , chemistry , crossover , metal , spin (aerodynamics) , salt (chemistry) , crystallography , stereochemistry , chemical physics , materials science , physics , organic chemistry , receptor , computer science , thermodynamics , biochemistry , artificial intelligence

A novel combination of S = 1/2 and S = 3/2 spin crossover and magnetic interaction between ligand and central metal exists in the iron( III ) complex 1 . Compound 1 is readily accessible from the corresponding dimeric thiolatoferrate( III ) complex and the corresponding pyridinium salt, and offers a further example for the diversity of properties of molecular magnetic materials.

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