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Synergy between Magnetic Interaction and Spin Crossover in an Iron( III ) Complex with an Organic Radical as Ligand
Author(s) -
Sutter JeanPascal,
Fettouhi Mohammed,
Li Licun,
Michaut Cécile,
Ouahab Lahcéne,
Kahn Olivier
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199621131
Subject(s) - pyridinium , spin crossover , ligand (biochemistry) , chemistry , crossover , metal , spin (aerodynamics) , salt (chemistry) , crystallography , stereochemistry , chemical physics , materials science , physics , organic chemistry , receptor , computer science , thermodynamics , biochemistry , artificial intelligence
A novel combination of S = 1/2 and S = 3/2 spin crossover and magnetic interaction between ligand and central metal exists in the iron( III ) complex 1 . Compound 1 is readily accessible from the corresponding dimeric thiolatoferrate( III ) complex and the corresponding pyridinium salt, and offers a further example for the diversity of properties of molecular magnetic materials.