Regio‐ and Diastereoselective Bisfunctionalization of C 60  and Enantioselective Synthesis of a C 60  Derivative with a Chiral Addition Pattern | Zendy

Nierengarten JeanFrançois | Zendy; Gramlich Volker | Zendy; Cardullo Francesca | Zendy; Diederich François | Zendy

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Regio‐ and Diastereoselective Bisfunctionalization of C 60 and Enantioselective Synthesis of a C 60 Derivative with a Chiral Addition Pattern

Author(s) -

Nierengarten JeanFrançois,

Gramlich Volker,

Cardullo Francesca,

Diederich François

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199621011

Subject(s) - enantioselective synthesis , chirality (physics) , malonate , selectivity , derivative (finance) , optically active , chemistry , stereochemistry , covalent bond , organic chemistry , catalysis , physics , chiral symmetry , quantum mechanics , financial economics , nambu–jona lasinio model , economics , quark

A versatile and simple method provides access to covalent bisadducts of C 60 with high regio‐ and diastereo‐selectivity. Starting from optically pure bis(malonate) derivatives and C 60 , a double Bingel reaction afforded optically active cis ‐3 bisadducts ( ee > 97%), whose chirality results exclusively from the addition pattern.

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