Nanostructured Metal Oxide Clusters by Oxidation of Stabilized Metal Clusters with Air | Zendy

Reetz Manfred T. | Zendy; Quaiser Stefan A. | Zendy; Winter Martin | Zendy; Becker Jörg A. | Zendy; Schäfer Rolf | Zendy; Stimming Ulrich | Zendy; Marmann Andrea | Zendy; Vogel Roland | Zendy; Konno Toyohiko | Zendy

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Nanostructured Metal Oxide Clusters by Oxidation of Stabilized Metal Clusters with Air

Author(s) -

Reetz Manfred T.,

Quaiser Stefan A.,

Winter Martin,

Becker Jörg A.,

Schäfer Rolf,

Stimming Ulrich,

Marmann Andrea,

Vogel Roland,

Konno Toyohiko

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199620921

Subject(s) - cobalt , oxide , metal , materials science , cobalt oxide , catalysis , spheres , pellets , transition metal , oxygen , inorganic chemistry , chemical engineering , chemistry , metallurgy , composite material , organic chemistry , physics , astronomy , engineering

Complete oxidation without formation of bulk CoO results when cobalt clusters stabilized with R 4 N + X − are exposed to O 2 . Since the resulting soluble, nanostructured cobalt( II ) oxide clusters (idealized representation below: dark spheres: metal atoms; light spheres: oxygen atoms; R C 8 H 1− ) do not penetrate very far into the pores of Al 2 O 3 pellets, unlike the Co clusters, these materials are potential shell catalysts.

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