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“Strangelove” in Cluster Chemistry: A New Class of Open‐Shell Transition Metal Clusters
Author(s) -
Gade Lutz H.
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199620891
Subject(s) - cluster (spacecraft) , transition metal , metal , chemistry , open shell , crystallography , shell (structure) , linkage (software) , chemical physics , stereochemistry , materials science , catalysis , organic chemistry , computer science , biochemistry , composite material , gene , programming language
Direct linkage of complex fragments of the classical Werner‐type with metal carbonyl complex fragments characterizes a novel type of open‐shell transition metal cluster, for which the term xenophilic has been proposed. These polynuclear complexes may display new metal frameworks with nonbridged metal – metal bonds; the structure of such a fragment ([Mn 7 (thf) 6 (CO) 12 ] − ) is depicted on the right.
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