BaYbSi 4 N 7 —Unexpected Structural Possibilities in Nitridosilicates | Zendy

Huppertz Hubert | Zendy; Schnick Wolfgang | Zendy

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BaYbSi 4 N 7 —Unexpected Structural Possibilities in Nitridosilicates

Author(s) -

Huppertz Hubert,

Schnick Wolfgang

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199619831

Subject(s) - tetrahedron , oxygen atom , crystallography , bridging (networking) , silicon , atom (system on chip) , nitrogen , oxygen , chemistry , materials science , molecule , computer science , optoelectronics , operating system , computer network , organic chemistry

Four silicon atoms have been connected to one central nitrogen atom for the first time in BaYbSi 4 N 7 . These N [4] bridges significantly extend the spectrum of possible linkages in Si ‐ N network structures of nitridosilicates. While oxosilicates are built up by SiO 4 tetrahedra with either terminal oxygen atoms or simply bridging O [2] atoms, the N [2] , N [3] , and N [4] linkages in nitridosilicates enable novel highly cross‐linked SiN network structures.

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