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π‐Pyrrole–Metal Complexes—The Missing Coordination Mode for Metal–Porphyrin Interactions
Author(s) -
Senge Mathias O.
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199619231
Subject(s) - porphyrin , pyrrole , metal , chemistry , photochemistry , polymer chemistry , organic chemistry
Metal–porphyrin π bonds such as those in 1 and 2 were hitherto unknown modes of coordination in porphyrin complexes. However, arene complexes of this kind were recently synthesized by Rauchfuss et al. ( Angew. Chem. Int. Ed. Engl. 1996 , 35 , 1833). Metal – porphyrin interactions of this type may also play a role in reactions catalyzed by metalloporphyrins.