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Synthesis of New Hybrid Materials by Intercalation of a Bifunctional Aminophosphane and Its Tungsten Pentacarbonyl Complex in α‐Zirconium Phosphate
Author(s) -
Bone Jonathon S.,
Evans David G.,
Perriam J. John,
Slade Robert C. T.
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199618501
Subject(s) - intercalation (chemistry) , tungsten , bifunctional , zirconium phosphate , ligand (biochemistry) , zirconium , chemistry , phosphate , stoichiometry , surface modification , inorganic chemistry , crystallography , materials science , organic chemistry , catalysis , biochemistry , receptor
Functionalization of a phosphane ligand facilitates intercalation of the free ligand and its tungsten pentacarbonyl complex (example shown bottom right) in α‐zirconium phosphate (section of structure shown bottom left). Syntheses of intercalated products with the stoichiometry [Zr(HPO 4 ) 2 (Q) x · y H 2 O] (Q = Ph 2 PCH 2 CH 2 NMe 2 , x = 0.46, y = 1.1; Q = (OC) 5 W(Ph 2 PCH 2 CH 2 NMe 2 ), x = 0.51, y = 1.5) are reported.