Self‐Assembly of a Circular Double Helicate | Zendy

Hasenknopf Bernold | Zendy; Lehn JeanMarie | Zendy; Kneisel Boris O. | Zendy; Baum Gerhard | Zendy; Fenske Dieter | Zendy

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Self‐Assembly of a Circular Double Helicate

Author(s) -

Hasenknopf Bernold,

Lehn JeanMarie,

Kneisel Boris O.,

Baum Gerhard,

Fenske Dieter

Publication year - 1996

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199618381

Subject(s) - ligand (biochemistry) , ion , torus , circular dna , chemistry , tris , crystallography , chloride , double strand , stereochemistry , dna , geometry , mathematics , biochemistry , receptor , genome , organic chemistry , dna repair , gene

The simple reaction of a tris‐bpy ligand strand with FeCl 2 leads to the self‐assembly of the unique cation 1 , which consists of a torus formed by five ligands wrapped around five Fe II ions in a double‐helical fashion and closed around a central chloride ion. This structure, a fivefold circular helicate, is a helicate analogue of circular DNA.

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