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Metalloporphyrins as Ligands: Synthesis and Characterization of [(η 6 ‐cymene)‐Ru{η 5 ‐Ni(OEP)}] 2+
Author(s) -
Dailey Karen Koczaja,
Rauchfuss Thomas B.,
Yap Glenn P. A.,
Rheingold Arnold L.
Publication year - 1996
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199618331
Subject(s) - ruthenium , ligand (biochemistry) , chemistry , crystal structure , crystallography , characterization (materials science) , x ray crystallography , stereochemistry , materials science , nanotechnology , physics , organic chemistry , catalysis , receptor , optics , biochemistry , diffraction
A new bonding mode is present in the title compound, in which a metalloporphyrin serves as a π ligand. The results of an X‐ray crystal structure analysis (shown on the right) and spectroscopic studies clearly show that the metalloporphyrin is strongly affected by the complexation.